姓名(Name):

朱敦如(Dunru Zhu)

性别(Gender):

男(Male)

职称(Professional title):

教授(Professor)

E-mail:

zhudr@njtech.edu.cn

工作地点(Office):

沉毅北楼607(Room 607, North Chenyi Building)

学习工作经历

学习经历(Education Background)

1979.9-1981.7, 六安师范专科学校(Lu’An Normal Institute)

1983.9-1985.7, 安徽教育学院化学系，本科(Undergraduate in Department of Chemistry, Anhui Education College)

1988.9-1991.7, 同济大学化学系，硕士研究生(M.S. Graduate in Department of Chemistry, Tongji University)

1998.3-2000.12, 南京大学化学化工学院，博士研究生(Ph.D. Candidate in Department of Chemistry, Nanjing University)

工作经历(Work Experience)

1981.7-1988.9 阜阳师范学校化学教师(Chemistry Teacher in Fuyang Normal School)

1991.7-1998.3 阜阳师范学院化学系讲师(Lecturer in Department of Chemistry, Fuyang Normal College)

1994.9-1995.6 南京大学配位化学国家重点实验室高级访问学者(Senior Visiting Scholar in State Key Laboratory of Coordination Chemistry, Nanjing University)

2001.8-2002.8 韩国浦项工科大学化学系博士后(Post-doctoral Fellow in Department of Chemistry, Pohang University of Science & Technology, Republic of Korea)

2002.9-2004.4 法国格勒诺布尔原子能研究中心博士后(Post-doctoral Fellow in Laboratoire de Physicochimie des Mètaux en Biologie, CEA-Grenoble, France)

2004.4-至今 南京工业大学化工学院教授（博导）(Professor in College of Chemical Engineering, Nanjing Tech University)

2012.8-2012.9, 瑞士洛桑联邦理工学院化学系，访问教授(Visiting Professor in Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland)

2014.9-2014.10, 美国弗吉尼亚理工大学化学系, 访问教授(Visiting Professor in Department of Chemistry, Virginia Polytechnic Institute and State University, United States)

2018.12-2019.1, 美国加州大学圣地亚哥分校化学和生化系, 访问教授(Visiting Professor in Department of Chemistry and Biochemistry, University of California, San Diego, United States)

研究方向

1. 纳米多孔MOFs材料 

   纳米多孔MOFs材料可通过次级建筑块（含过渡金属和镧系金属离子）和有机配体的自组装来合成。借助该法本课题组合成了一系列新的1D-3D多孔纳米MOFs材料并研究了它们的拓扑结构和各种性质（稳定性、气体贮存、染料吸附、非线性光学、磁性和质子导电等）。

2. 含三芳基三氮唑的自旋交叉铁配合物的合成和磁性研究 

   该方向涉及一系列新的三芳基三氮唑配体及其铁(II)配合物的合成和结构表征。磁性研究表明一些铁(II)配合物具有自旋交叉性质，能在较高的温度下发生突跃式的高低(HS-LS)自旋跃迁，表明它们是一类新的分子开关材料，在信息技术上有重要的潜在应用价值。

3. 生物酶模型物——多核配合物的研究 

   多核锰和铜配合物是研究生物体系中的含锰和铜酶的重要模型化合物。我们设计合成了一些新的多核锰和铜配合物，它们的结构已经单晶X-射线衍射表征。磁性、电化学和谱学性质研究表明，它们是一类重要的含锰和铜酶模型物。

Research Interests:

1. Porous metal-organic frameworks (MOFs) materials 

   Porous MOFs materials can be synthesized by the self-assembly of some second building units (SBUs) containing the transition metal or lanthanide ions with organic ligands. A series of novel porous MOFs materials (1D-3D) have been prepared by this method in our group, and their topological structures and properties (stability, gas storage, dye absorption, nonlinear optical activity, magnetic susceptibility and proton conductivity) have been systematically investigated.

2. Syntheses and magnetic studies of iron(II) spin-crossover complexes with triaryltriazoles

   This project involves the design and synthesis of a series of new triazole ligands and their corresponding complexes with the first transition metal ions. These complexes have been characterized by X-ray crystallography, EXAFS, IR, UV and ESI-MS. Mössbauer spectra and magnetic studies have demonstrated that some of iron(II) complexes show an abrupt high spin-low spin (HS-LS) transition in high transition temperature, indicating them could be a kind of novel molecular switching material and potentially used in molecular information technology.

3. Polynuclear complexes with potential biological significance 

  Polynuclear manganese and copper complexes are good models for metal-containing enzymes in biological systems. Some novel polynuclear Mn(II) or Cu(II) complexes have been synthesized and structurally characterized by X-ray crystallography. Their magnetic, electrochemical, spectral and biological properties are currently investigated.

代表性成果

1. Jie Yang, Shunlin Zhang, Zhe Feng, Ying Cao, Dun-Ru Zhu*, Dalton Trans., 2021, 50(34), 11975-11985.

2. Xin He, Xin Wang, Tianyu Xiao, Shunlin Zhang, Dunru Zhu*, Inorg. Chem., 2021, 60(1), 9-13.

3. Run-Kun Kang, Ya-Yu Dong, Jia-Peng Cao, Xi-Ming Luo, Ze-Yu Du, Dunru Zhu*, Yan Xu*,  Chem. Eur. J., 2021, 27(4), 1301-1305.

4. 朱敦如，黄未来，吴远华，沈旋，“荧光化学传感器化合物及其制备方法和用途”，发明专利号ZL201710511107.6，授权公告日：2020.2.21

5. Shunlin Zhang, Sheng Gao, Xin Wang, Xin He, Jing Zhao, Dunru Zhu*, Acta Cryst. B, 2019, 75(6), 1060-1068.

6. Chuantao Liu, Fang Wang*, Ting Xiao, Bo Chi, Yuanhua Wu, Dunru Zhu*, Xiaoqiang Chen*, Sens. Actuators B, 2018, 256, 55-62.

7. Jing Zhao, Xin He, Yuchi Zhang, Jie Zhu, Xuan Shen, Dun-Ru Zhu*, Cryst. Growth Des., 2017, 17(10), 5524-5532.

8. Xin Wang, Tao Qin, Song-Song Bao, Yu-Chi Zhang, Xuan Shen, Li-Min Zheng, Dunru Zhu*, J. Mater. Chem. A, 2016, 4(42), 16484-16489.

9. Jie Zhao, Xin Wang, Jing Zhao, Rui Luo, Xuan Shen, Dunru Zhu*, Su Jing*, CrystEngComm, 2016, 18(6), 863-867 (Back Cover).

10. Tao Qin, Jun Gong, Junhan Ma, Xin Wang, Yonghua Wang, Yan Xu, Xuan Shen, Dunru Zhu*, Chem. Commun., 2014, 50(100), 15886-15889.

更多信息请见课题组网页(Please see our website for more information): http://lmc.njtech.edu.cn